If ev is now correctly charged on the air side - & holding, then you need to stop the leak at the filling loop by capping although this will need removing each time you need too top up (replacing would be better for water regs). You also need to be absolutely certain that the 'copper' relief pipe is not discharging! The condense pipe should be white and go into a drain or soak away via waste pipe if a long run to drain. Even though you replaced the PRV, they can become 'unseated' when activated (which yours is likely to have been due to the undercharged ev). This needs to be either checked for watertightness by trying to reseat or replaced.
