i will postulate that your timer is by the meter, and that you have two cables from the meter(s) to your two consumer units, and that the off-peak consumer unit will (should) probably be timed to come on overnight. The upper immersion heater supply will be live 24 hours, subject to your local switch.
That makes sense. There are two switches, and on one of them, the red neon light was off, and the immersion heater did not work. I thought i had done things incorrectly but if the electricity only flows at midnight, then the neon light will turn on later tonight and the bottom heater should start working.
Is your tapwater scalding in the mornings?
No, it isn't scalding but it may be less hot in the evenings now you mention it

