I have balanced the radiators
So did I, worked A1 in mother's house but did not work here. I did the fine-tuning by reading the TRV display,

the current should not exceed target, it can easily do this while warming up, overshooting, and harder to get spot on if the TRV is on the return, but it did work, the anti-hysteresis software seemed OTT, so would set to 22°C at 7 am and 20°C at 8 am to get around the software, took some time to get right, but it did work spot on, only when sun shining through windows would it over shoot. I was rather proud how well I had set it.
Then I moved here, and the TRV head does not work with an on/off oil boiler with micro bore, as well as they did with a gas modulating boiler, with 15 mm pipework. Main problem is the hall cools too slowly, so having the main thermostat in the hall did not work, and the Nest Gen 3 thermostat needs a 12 volt power supply from the hub, so not really an option to reposition it.
So fitted a Wiser hub in parallel, and Wiser wall thermostat in the living room, and TRV in the wife's bedroom. Living room now at the temperature I want, but a bit slow re-heating, but think that's simply down to the size of the radiators.
Of the four homes I have lived in, every one was different, home one hot air worked very well but expensive to run (1970s) Next water open plan, up-stairs got too hot, TRV heads upstairs only cured that, open-plan house, added extra radiator downstairs, but thermostat in arch between both rooms, and it worked well. (1980-2018) So mothers was a problem, cured by fitting a TRV on hall radiator with the hall thermostat. And this home sorted by fitting multi-thermostats. Seems no one system suits all.