As I said in #61, I think there is some liquid refrigerant when the whole thing is at ambient temperature. When the compressor has just stopped so the freezer is at -18° more of it will be liquid..
Indeed - but, as I said, unless the pressure 'when the whole thing is at ambient temp' is high enough for an appreciable proportion of the refrigerant to be liquid, there would actually be fairly little refrigerant in the system - and does not the ability of the system to 'move' heat efficiently (at least, the rate at which it can do that) depend upon how much (mass) refrigerant there is?
I know how propane tanks work! It's a liquid at storage pressure and the pressure stays constant (at a given temperature) as the contents are used, until the liquid has evaporated. About 8 bara at 20°. Unlike an oxygen (or hydrogen or nitrogen) cylinder where it starts at 200 bar when full and falls steadily as the gas is used.
I'm sure you do know how they work, but I suspect that some (including some who may be reading our mutterings!) may not.
I was trying to make the point that, like a propane tank, refrigeration appliances presumably contain a mixture of liquid and gas (with the liquid turning into gas 'as needed', whereas the other sorts of gas you mention (oxygen, hydrogen, nitrogen {hence all air} etc.) are stored entirely as compressed gas, presumably because of their very low boiling points at any credible pressure? However,as above, I suppose the major part of my point was that unless there an appreciable proportion of the refrigerant is liquid, there's probably not going to be much total mass of refrigerant in the system.
It also says, below minimum design ambient temperature (+10° in my case) "functional irregularities may occur during automatic defrosting of the refrigerator interior". Maybe that's part of the explanation. I think it means the freezer, which has automatic defrost. The fridge has the usual condensate drainage.
Maybe we're partially getting somewhere, since the potential problem they are mentioning is a lot more benign that the "freezer won't work in an outhouse" story we so often hear being thrown about. Mind you, I have a feeling that that story has been around for a lot longer than 'self-defrosting' freezers, so I'm not sure!
However, this does make me wonder whether (supported by my own long experience of 'no problem') my own suspicions may be right - namely that there is perhaps a fair bit of 'mythology' associated with all the stories/'warnings'?