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Doggit
Although you're using a breathable membrane, a 25mm air gap is still a good idea, so you'd need an inch batten under the joists. By the time you've added the weight of the celotex and plasterboard, the existing 3x2s won't be strong enough, so I suspect this is why he's doubled them, but I'd say he's done it the wrong way round, but adding the 3" to the top of the existing joist won't give the same structural integrity as a new 6" joist. Chat to your local BCO to see what they'd specify without an independant BC.
And using 75mm insulated PB means you're going to be using very longs screws, so I'd glue and screw 50mm battens to the existing joists, tack a 25x25 batten by the membrane to give an air gap, then use 100mm celotex, and then 50+pb over the top.
And using 75mm insulated PB means you're going to be using very longs screws, so I'd glue and screw 50mm battens to the existing joists, tack a 25x25 batten by the membrane to give an air gap, then use 100mm celotex, and then 50+pb over the top.