I see the problem, but not the solution, the problem is the boiler is analogue, and most zone valves are digital i.e. on or off, so what is needed is enough zone valves so the net result emulates a analogue control.
The UFH is split into many zones each one with water at around 30°C each time the water cools some more hot water is added, and the water is pumped around in a circle of just the UFH with an independent pump to the one which pumps main CH water around. So although the valves are digital the net result with a bank of 10 valves on the manifold is near enough analogue.
The UFH will not react fast enough to compensate when the sun shines through a window, so you need the radiators to act fast, so they can turn off fast when sun comes out, so need electronic TRV heads to work fast enough, so if you have electronic TRV heads, you can set zones without using a zone valve, so the on/off zone valve becomes redundant, so you now have one thing left.
As the weather gets warmer you want the whole system to turn off, tradition was a single wall thermostat placed in a room normally kept cool, with no outside doors, or alternative heating, on the ground floor, if such a room does not exist, then fit more than one you can fit as many as you like in parallel, main thing is they need to be set higher than the TRV in that room, they only work when weather improves, they do not regulate room temperature, all they do is stop the boiler cycling on/off through the summer months.
Old house I had two wall thermostats, one in kitchen and one in hall, neither ideal rooms, but as a pair they worked well. Did not want one in living room as living room kept too warm, want the wall thermostat at around 18°C so on warm days boiler does not even run first thing in morning.
If going to the expense of UFH then the cost of wifi TRV is not that high, between £40 and £80 each depending on the make, these can replace the wall thermostat, there is one make called Hive where the TRV head sends a 'demand for heat' to the wall thermostat, so if the wifi heads are put in coolest rooms, does not need to be every room, the wall thermostat also in a cool room and between them they can insure the boiler runs when required, you can use cheap eQ-3 at £10 each in rest of rooms. If when in use you find one room cold, just add a wifi TRV to that room.
TRV heads do come in different quality, think Drayton is about the best, with algorithms built in to work out when to turn down so rooms heat up fast but do not over shoot, however not found a single make that does everything, EPH wall thermostats can be set master/slave and work with OpenTherm with many wall thermostats, but no link to TRV heads, Nest has a really good algorithm but again does not link to TRV head, Hive is rather basic with no OpenTherm, but does link to TRV heads, the list goes on.
The guys who fit central heating call themselves heating engineers, and to be frank to work out the best most economic way to heat the home will likely mean training to degree standard, as an electrical engineer I realise the skill required to select the right product and set it up to work well, and also realise I don't have that skill, if designing a heating system was easy the guys doing it would not need to train to degree standard, I had three attempts at mothers central heating before I got it right, this house still not right, electronic TRV's in every room helps, but is not the whole solution.
So if your going to DIY expect to make errors, I know here the wall thermostat (Nest Gen 3) was not in hind sight best option, I feel not my error, when I bought the Energine TRV heads I was told they worked with Nest, but when I came to pair them up with Nest was told Nest has withdrawn support. So they work well enough not to be worth changing, but not A1.