2 x 12 volt in parallel is 12 volt, in series it is 24 volt, and commercial chargers for that size are normally around 0.8 amp auto dropping to 0.1 amp and zero when recharging but when in stand-by often fixed voltage from 26.8 to 30 volt depending on the battery use, for example a flood lamp which only lights on a power cut 26.8 and a stair lift which is used daily 30 volt.
It also depends on battery type, even just lead acid with out considering other types, we have flooded, gel, and VRLA/AGM (valve regulated lead acid or absorbed glass mat) when you go to others there are all sorts of methods used like detecting peak voltages as constant current to turn off charge and having heat sensitive switches strapped to battery. Also computer controlled where it remembers how much charge is in battery.
Because it is so complex to work out charging rates, the norm is to buy ready made chargers.