So I managed to get into the loft and work my way to the edge of the house where the wall s and the build up of the wall in the loft doesn't add up.
I have ceiling plaster board which goes towards the brick wall and then behind the wall there is a brick which looks like a air brick, isn't this where the cavity would normally sit...?
You will be struggling to form any opinion, by trying to look down, from inside the loft, the roof angle will prevent it. You would need to remove roof tiles at the eave, then see,
Your insulation choices, are to add insulation to the outside, or the inside. Outside, means your heating system would need to heat more of the fabric, before you feel the benefit of the heating, but it will give up the warmth, later, when the heating is off. There are a variety of methods of doing this, but the entire job would need to be done, as one.
Insulate the inside, and rooms will warm up quicker, and cool faster. That will involve battens fixed to outside walls, insulation between them, then plasterboard over the top, obviously you will lose some space in the process, but it could be tackled one room at a time, as DIY.