The best way is if you put ch only on see if there is a live at room stat,
live in and neutral then switch stat on and and try live switch and neutral
this sends live feed to junction box and from there down the white wire to 3 way valve then out of valve on orange wire to pump and boiler.
if there is no live at room stat the programmer is faulty
if it is the hot water side switch programmer on dhw only go to junction box test brown and earth for 240 v if no volts programmer faulty if there is vaults check black ans orange these are normally in the same pin and earth if no volts the cylinder stat is broke if there is volts the 3 way valve is faulty.
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