I have disconnected all of the neutrals and the one from the master fused CH switch is the problem.
With the neutrals still disconnected I opened up the switch and I have 242V red to black going into the switch then when the switch is on 242V on the blue wire.
Note that the brown wire has a piece of insulation missing
The blue wire is in fact attached to the L terminal of the switch...
With the switch turned on the brown wire is connected to earth, however my multimeter makes a warbling noise rather than a continuous beep, like it is connecting and disconnecting very quickly.
If that brown is connected to Earth as it seems to be then changing it to Live would not be a good idea without altering other connections.
You appear to have L & N into that switch and just the blue wire leaving it. so no N to system.
This does not make sense as you say that the valve operates with the head removed.
If it is a Honeywell type valve with 2 fixing screws for head to body, sometimes over-tightening these screws can cause the motor to bind
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