It appears there is confusion between an optimiser (delayed start) and a weather compensator.
Optimisation is different to delayed start. Optimisation will delay the boiler's start to reach the start occupation time temperature setpoint and "increase" it too. The better versions will optimise the off period too (it works out when to turn off the boiler to keep the room setpoint constant right up to the off time). If the building is at setpoint, even at the start of occupation time, some will still keep the heat off. The simpler versions will always bring on the heat at the start of occupation time.
Delay start is just that, it only delays the start and always brings in the heat at start of the occupation time.
Weather compensation is varying the flow or return temperature depending on the outside temperature. The lower the outside temperature the higher the flow or return temperature (some sense the flow temperature, others the return). The flow or return temperature can be trimmed up or down with room temperature influence to maintain a room temperature setpoint.
If the weather compensation and delayed start are separate units, there should be no problems, condensing boiler or not.
When the two are integrated, the room temperature sensor can be used by the weather compensator to trim up or down to suit. The delayed start can use the compensators outside temperature sensor. If OpenTherm compatible, then instead of switching out the burner (on-off control) the burner modulates giving more precise control and better efficiency when using a condensing boiler.
Only a few boilers have OpenTherm compatibility, if you can get one I advise to get it. Keston are OpenTherm, Atmos and few others. I believe German Vailant's UK models are not. OpenTherm really do make a difference in control and you are not stuck with a expensive dedicated makers kit (like Vaillant, Glow Worm, etc) as OpenTherm means anyones controls will work on your boiler.
The sooner the UK makers adopt OpenTherm across the board the better the control system will be on UK system. The cheaper it will be too, as third party makers will compete supplying the controls. A simple OpenTherm room thermostat will modulate the boilers burner to maintain the room temperature. That means a condensing boiler may be modulating to give only 35C flow temperature, giving exceptionally high condensing efficiency. But only if the boiler can modulate down to a very low kW rate.