Whilst you wait for some one to change some of you pipe work as tamz has suggested it would give an improvement to your perceived problem if you converted you S/Y plan to DHW priority,(W plan) this would allow the boiler to heat the cylinder whilst isolating the heating circuits until the cylinder is heated.
Having said that, if the cylinder and heating zones are on separate time clocks you could stager the start up times to achieve a similar result when starting from cold.
Have had a quick look at the Installation and servicing instructions and it would appear the 40CDI does not have the facility to allow two different boiler flow temperatures for the cylinder and the heating circuits which is a shame as this would allow you to have reduced you gas consumption.
Tim.