Hm, it's all very strange, isn't it.
A fully pumped system, which must have water in the F&E because that's been thoroughly checked, and with no blockage in the cold feed because that's been thoroughly checked, and with no air lock above the pump because that's been thoroughly checked, and with completely clean system water because that's been thoroughly checked, and a fully working pump because that's been thoroughly checked, and the boiler is producing heat, and yet that danged hot water just doesn't want to get pumped around anywhere.
There's no possible explanation for it not working, given that everything has been so thoroughly checked. It's a mystical and mysterious mystery. It's almost as though the pump just isn't pumping, but that's just crazy talk.
Best check the wiring of the MZV, and the programmer, then fiddle with some TRV pins. Oh, and check the age of the boiler and the availability of parts - that'll get the water circulating again.