That's to do with HW from the taps and shower.
In #23 you said "My current vented system's F&E pipe is way less than that (2.5m), and the system is full of sludge, and one of the radiators has rusted through. It is around 25 years old", which I assume is the primary circuit. Is the 2.5m a pipe length? Sounds like it needs a good clean, Powerflush or something, and replace the leaking rad. Then add the correct dose of inhibitor, and you should be OK for years. Of course you can convert it to a sealed system if you want, but I wouldn't.
I plan to replace current my vented system with a thermal store, preferably sealed.