You dont need any perimeter insulation or expansion room, but if the walls are solid and don't have any insulation in them, then you may want to include 5 or 10mm of foam to pervent any condensation. Bear in mind the skirting width though, as you dont want any edge insualtion showing, and may need a firm base for carpet grippers
Make sure the screed is reallyreally dry. The slab will need to be dampened to ensure a firmm bond.