A very interesting post. There's a lot there so I'll answer by writing bits as they come into my head.
Q - Are the walls covered with gypsum based plaster and modern paint? From the construction you describe it sounds like the house may have relied on pre-cement ie Lime construction (c1900?) as part of its damp control. There's others on here that will answer that better than I will. But sometimes people have introduced problems into an older building by using modern materials. Modern materials prevent the wall from breathing as they were originally intended to.
R – The house was constructed using pre-cement (lime), but t here is no gypsum based plaster. The base structure is in good condition. The more recent walls finish are made with cement mortar plaster and painted with white water based paint. About the materials, care was taken to avoid materials that could make difficult the wall breathing.
Q - I take it that the old plaster was removed and replaced after the damp system was installed. The salts in the plaster may have been hygroscopic, attracting water from the atmosphere. So even if the underlying damp problem had been cured this may have continued to be a problem. Again others might offer more on that.
R – More recently, with the installation of the Lectros system, the old plaster was removed and the walls were cleaned for eliminating remaining salts and replaced with new cement plaster.
Q - The walls are quite thick and also don't sound to have a cavity. Did you use the deep anodes that Lectros do to enable good coverage of the wall through its thickness? What is the coverage of the anodes in the walls at the moment? What distances are between them? At some point the effect of an anode must diminish and I would think that the rate at which it does depends on wall conditions. I have no solid data for what their spacing should be, only noting that the installation manual says to reduce the distances for problematic walls and that the anodes supplied come on 1M spacings, which I assume to be the maximum distance for average conditions.
R - I didn’t use the long anodes because I read in the technical instructions that for thickness up to 60cm the normal anodes would satisfy. However they were placed so as to be in half the walls thickness. The spacing between anodes would result from that condition (<1m).
Q - The earth rod sounds very deep. 3M is quite long for a rod. But its length is determined by ground conditions, the idea being to ensure that the rod is in permanently conductive ground and that often means that it sits in damp/wet ground and probably has gone into the water table. What are the ground conditions like? How low is the water table below the level of the bottom of the wall? Have you ever tested the effectiveness of the rod?
R – 3m is a standard length for the rod we can get here. Difficult to know where is the water table.
How shall I test the effectiveness of the rod?
Anyway, the current readings around 25 mA suggest that the system is operating in good condition.
Q - If you are connecting a mains powered oscilloscope to the system you may change the system performance and the signals that you're trying to observe. Many oscilloscopes have probe grounds which are connected to the mains earth.
R – The oscilloscope I use is a PC oscilloscope that uses 5V supply from the computer’s USB output. I think it is galvanically insulated from earth.
Q - It is interesting to read what currents you have in the system. At the moment I don't have any data on the currents in the systems I have put in, neither are in my house. If I can get such data I will let you know. I would of expected the current to fall to some minimum amount. Seeing your readings makes me wonder has the system done what it can and has now settled to its final value.
R – It is not easy to interpret the results. Anyway I send you pictures of the data obtained with the oscilloscope.
1.gif – Shows the output voltage from the power supply, disconnected from the anodes&catode. It’s a typical full wave rectified voltage (with some 50Hz hum superimposed).
2.png - Voltage between anode and cathode with the system connected.
3.gif – Voltage on the wall when anodes and cathode are disconnected from power supply.
Q - Regarding possible current variations in the readings due to an unsmoothed DC supply. I did wonder about the effect of an unsmoothed output when I saw it on the oscilloscope. I would expect the output to change once the system was installed but quite how it would I'm not sure, again if I can, at some point I will scope the output with it connected to the system.
R – See curves.
Q - Regarding the sampling of the meter and a possible error due to it. What I think you're referring to there is possible aliasing distortion. Although I would of thought you'd see a fairly regular cyclic variation due to the product and drift of the two frequencies? Different meters measure varying waveforms differently. Once the waveshape becomes non-sinusoidal then things could get quite complex. If you doubt your meter's interpretation you could filter the output to give a more stable reading by putting it through a diode and then to a resistor in parallel with a capacitor. Meter across the capacitor. Pick your time constant to be perhaps 10x the 100Hz of the output ( so about 0.1sec) and drain resistor to be an insignificant load on the system. Depending on where you connect the circuit it would read voltage or current and with a value that was near peak.
R – Your comment is correct, though I see some difficulties on using a diode, because the forward voltage would not be attained (the voltage drop in a 1ohm resistor used for current readings is not enough) . However seeing curve 2.png, there is clearly a DC component (2V – this might be the so-called backwall voltage) which is superimposed with an alternate 100Hz component, possibly responsible for the short time variations on the digital meter. I’ll have to study this in more detail.
Q -The GANN moisture meters and similar have to be used with care. They can be effected by all kinds of things, not just damp. In this instance was the system turned off before you used it? I don't know yet if they're effected by the system when it's on.
R – No, the system was on! Good that you thought of it!
I’m going to check this. Thanks for reminding! The Gann system works on the capacitive principle!
Q - It would be interesting to see your oscilloscope results.
R – I’ll send them in annex.
Some thoughts on possible ways to investigate the system performance.
R – GOOD Ideas!
Q - Is it possible, using the earth rod as a reference, to probe voltages in the walls in order to see more of what is going on? Different heights and different locations to build a map?
R – I guess it is possible to connect one probe to the cathode and the other one to some sharp tool to pick up the voltage at the wall and make several readings.
Q - Possibly add or subtract an anode (or anodes) to see if the change is reflected in the current in the system. Then you'll know if changes are having an effect.
R –Difficult to reach the anodes since they are cemented in the walls. However, I think I could make an experiment by connect the end of the titanium circuit to its beginning, closing the loop with low resistance copper wire. This will reduce the resistance of the loop because the titanium is more resistive than the copper.