Success!! Changing the dip switch has allowed seperate control of HW and CH, i can't believe i've been running the same together all this time. Many thanks fopr your help again.
Regards to the wiring, i've attached a very crude diagram (the best I could do). Just a few things to note: The light gray cable in the diagram is actually white. I suspect cable 1 is the room thermostat Cable and Cable 2 is the cycliinder thermostat (only by determining where it's corresponding wire ends up connecting to on the programmer). FCU is fused connection unit. And i notice the 2 zone valve has only 5 cables not 6 (the cable directly from the valve actually goes to a junction box first which looks like it was put in to extend the cable length to the main junction box but i haven't managed to look in there to see if the 6th cable is present). Also, some pics of the mess of cabling....
Hopefully from this it can be shown how to wire the Nest base.
Thanks again for your help..