Hah, no.. but I was!
Spray a test batch or on an offcut of cable. I think it highly likely nothing bad will happen; if you dug into it you’d probably find that the aerosol nozzle / stem of the spray can is also PVC, which would be a poor thing to make a nozzle from if the paint attacked it
Spray from afar and use plenty of coats. Sidebar, the last spray I used was water based too