I am particularly interested in the pump and electrically operated valve, since I think the water is not circulating properly
If the pump was not working, the boiler would overheat and cut out.
If the pump was running too slow the same thing would happen and if set too fast the water would not reach temp. But the OP says he has not changed the pump speed.
If a motorized valve was not opening fully, you would get the same effect as a slow pump, i.e overheating.
I think it may be either a faulty boiler stat or the heat exchanger furred up.