Replace the auto air vent - with any trapped air and an old blocked aav your going nowhere.
Is the pin between the water section and the cam adjusted correctly? If not the cam will not rotate sufficient to reverse the diff. pressure on the diverter.
Is the DHW microswitch adjusted correctly? - again it has to be set correctly.
Does the diverter valve operate and move sufficient to operate the 2 microswitches?
Are the microswitches correctly adjusted?
If so perhaps the problem lies in the hydraulic gas valve operator - maybe there is insufficient diff. prerssure in DHW mode to move the pin.
Within the servo valve above the water section is an arrangement of ceramic discs (similar to quarter turn taps). Sometimes due to scale/debris these discs do not allow the full differential pressure across the diverter - in effect the discs let by since they are no longer in close proximity. Either carefully strip down and clean or replace.
Next check the control tubes are clear and the restriction in the banjo connection.
Next strip down the diverter and check/refurb
Unfortunately manuals are not particularly helpful. A Haynes manual will show you how to strip down and rebuild a car gearbox but it won't tell you how to check for wear on the baulk rings and cones on the synchro hubs. Boiler manuals are no different - its all down to experience.
