start with the pressure problem. Expansion vessel not functioning properly.
This may be because sludge has blocked the small pipework into it, or it might have just need recharging or the membrane may have fractured, or the shraeder valve may be leaking.
First off depress shraeder valve (car tyre inflation valve) in top of large circvular orange metal part hidden in the back of the boiler accessible from above to the back. If water comes out you need a new expansion vessel. Buy a cheap generic (£12) one 8ltre minimum and mount it near the boiler t it into the return pipework near the boiler. Or pay £60 or so for manufacturers part, may need to remove flue to get it down the back of the boiler, but if flue is to side you are in luck.
no water? did a little whiff of air come out then stop? Pump it up. First isolate flow and return, drain boiler until just no pressure, no more. Inflate vessel with bike pump (40 good pumps fast) pressure guage should be approaching 1 bar, but may just be 1/2 bar, keep pumping unitl 1 bar. Undo pump very quick so as not to undo all your good work. Listen to ensure schraeder valve has sealed, may require a push in to get it to seat good. Wait a while to make sure it is a good seal.
Open flow and return, open filling loop, chargre system to 1 to 1.5 bar.
Make sure auto air vent is open and doesn't leak (change as required)
You still may have a blocked pipe, see if this works and be ready to dissassemble the thin pipe up to EV and clean crusty hard sludge out.
Check pressure relief valve isn't dripping consequent to being operated with dirty system water holding it apart. Change as required.
Hot water performance might then be OK but report back for phase two.