Because tariffs change region to region, hard to compare London prices when I am on Mid-Wales prices. But I did look at the rates, and some did seem silly, I can't see what is the difference between a battery which is built into a car and connected to the grid, to one in a house and connected to the grid, in both cases energy is being stored for latter use, and so to give a EV user 5 hours and the one EV 3 hours off-peak one would expect the 3-hour one to be cheaper, but it's not. The Flex tariff offered to solar panel users is not one I would want to use.
My son tells me his EV tariff, means Octopus is turning his charging on/off as odd hours, so he can't plug in the EV and say it needs 70 kWh so it will be charged in 7 hours, the "intelligent go" means he does not know when he can "go" with a full charge.
I remember many years ago, looking at some council houses in Lixwm where the storage was central, with fans to put the heat into rooms when required, and a friend living in one, told me the bricks could stay hot for a week, and each room was thermostatically controlled, and for those homes, it would not have mattered if the off-peak was 3 hours, 5 hours, 7 hours or 10 hours as the heat store would last out, and house very well insulated, this was late 70s, so not new technology, the problem with the off-peak heating is the storage radiator not the tariff, which once fully charged, will not retain the charge even with everything turned off output wise, for even 24 hours.
We have seen bad heating systems installed throughout the ages, with coal fires and no ducts to bring in combustion air, and if sucked the air from the room in general causing massive drafts. My last house was designed to be heated with a single central gas fire, with open-plan house, that also did not work, we soon installed central heating.
The net result is, every homeowner has to work out what suits them. There is no magic system which suits all. A late friend of mine, had a home in the middle of 12 acres of woodland, and he said he was not growing enough wood for his needs, the council issued him with a green waste bin, and as he said, it would not even fit one tree. Not sure, I believe him, I have two green bins, and I keep the thick stuff for the BBQ, not a large garden, but the wood is mounting up.
But to work out which tariff would best suit my lifestyle was not easy, there is no one suits all, and there is still a lot of guess work.