There is no other control circuitry, so would connecting a live supply to the switched live out cause the welding of contacts together?
before you try anything as drastic as desoldering the relay get inside (by cutting/breaking if nessacery) the relay and see if you can find the welded contacts and reseperate them.

I am concerned that the Radiator circuit zone valve could send a live via the orange swicthed live into the switched live output on the relay.
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