Thanks for finding the diagram.It does seem that way. Maybe this could help from Intergas? https://www.intergasheating.co.uk/app/uploads/2024/03/Ref-1_X-Plan-Leaflet.pdf
It's actually a beautifully simple system
(Just to avoid any earlier confusion, the orange and grey wires from the zone valves arent connected to the 24V terminals).
Simply, if the H/W timer is on; it has opened the circuit on X4 terminals 9 and 10. If the tank stat (NTC) calls for heat, a DHW switched live is output on the mains voltage terminal 5 (through an overheat stat).
This drives the Normally Closed DHW valve open, providing HW flow to the tank coil.
When this valve opens fully, the grey and orange wire from it provide a switched live to the C/H Normally Open zone valve.
This valve is then driven closed, cutting off the C/H.
Any signal wires of this valve are unused.
The change in DHW temperature is managed internally by the boiler.

