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What’s the best way to clean a copper pipe that I want to cut and add a compression fitting to

The pipe is old with just a bit of emulsion paint on it

It's my cold water so I want it nice and clean, would wire wool do it?
 
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Fine emery cloth to remove the bulk of the paint and finish with fine grade wire wool.
As @DetlefSchmitz says, wear gloves when using the wire wool. It's a pain, (literally), when little bits get into your skin.
 
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Stop using fairy liquid and man up ;)
When I worked in engineering, my hands were so rough and hard I could hold them under very hot water, (+50ºC), and it felt warm. Didn't stop those little bits getting into your skin and start irritating you a few days later. But it's not a surface irritation that you can scratch as it's sub-dermal.
(As for Fairy Liquid, we have a dishwasher. ;) )
 
Excellent, I've cleaned it up nicely with a cheap scotchbrite-type pad and some wire wool :)

What's the best way to cut into the pipe without filling it full of swarf? I can't get my pipe cutter in as its too close to the wall
 
Just flush it through at a tap afterwards. Don't let anyone flush a loo while you work.
 
Excellent, I've cleaned it up nicely with a cheap scotchbrite-type pad and some wire wool :)

What's the best way to cut into the pipe without filling it full of swarf? I can't get my pipe cutter in as its too close to the wall
Put your little finger in it while you are cutting it!
Follow me for more useful tips!
 

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