Sorry, but you initially stated it measured 22mm, now you state 20mm?!?!
If it is MDPE it is probably 20mm outside diameter.
If it is imperial alkathene it is probably 1/2" inside diameter.
As stated previously, Philmac fittings are designed to fit both types of pipe.
22mm copper compression fittings will almost certainly not work on your 'plastic' pipe. Plus I think you need to be extending in 15mm copper, not 22mm, as you almost certainly have 20mm/1/2" pipe in situ now, the equivalent bore size to 15mm copper (thereabouts).
The nuts on the stop cock might have a size stamped on them, or even on the stop cock body.
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