Rock wool comes in varrying thickness 50, 65, 80, 90, 100mm and up.
You need a full a fill as possible, have you considered.
What area do you live in? http://bmdinsulation.com/rockwoolinfo.htm
Insulation works because it is full of air which 'traps' the heat. If you squash thicker insulation into your gap you'll squeeze out the air reducing the effectiveness.
Use something that is 50mm thick, rockwool is Ok, celotex is better.
Or use deeper studs and thicker insulation.
Yes, of course you can use mineral wool but I think you must either use rigid batts or fix loft insulation blanket at the top to stop it collapsing into the bottom of the cavity. Your Building Engineer or Building Inspector might require a vented cavity adjacent to the brick.
strip plaster from the brick
seal the brick inner surface with a concrete render (e.g. Soundcoat)
50mm treated battens at 600mm centres
50mm Celotex on top of the battens (taped joints)
19mm wood strips (holding Celotex in place and providing service void)
plasterboard
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