I'd also bet the two valves are wired in parallel, for lower flow resistance, it's common.
Only problem comes when one of them fails - you tend not to notice!
Vent on the return?
What size is the boiler?
Currently the Feed & Vent are close coupled in the flow before the pump, the feed is nearest the pump so looks Text book to me 35mm pipe should be more than adequate for a 32Kw system!! there's a lot of carp being posted on this thread!!
To many mountains being made out of a mole hill here!!!
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