Jim, fair play to you. I can understand your reasons for wanting to DIY the job, you may be a little short sighted in your reasoning behind not wanting to shell out for a qualified electrician but that's your choice.
It sounds to me as if you're going to do the job yourself either way, so rather than lecture you about part P testing and certification of which you are already well aware, perhaps we could offer some more constructive advice. This is, after all, a DIY forum, and there will be hundreds of people out there doing DIY work every day who aren't even remotely competent or aware of the regulations governing such work.
As we've already mentioned, it's important you determine what type of supply comes into your house. If it is TN-C-S (PME) then the neutral and earth tails to your CU should terminate into a single neutral block at the service head. A TN-S supply will have seperate incoming phase, neutral and earth at the service head, and a TT system will have some form of local earth, most likely an earth rod.
Assuming your supply is not TT and you understand how to wire a split load CU, things should be relatively easy for you. Before starting the work you should make sure the bonding in your property is up to scratch (see the WIKI). During the work you should at least conduct some very basic tests. For a DIY job I would feel a little happier if you at least check all your ring circuits and make sure there is L-L, N-N and E-E continuity between both legs of the circuit with a meter, and test all sockets with a martindale plug in.
If the information on the WIKI and this forum doesn't prove enough for you to do the job, don't even attempt it. All the above assumes at least some level of competency with regard to the task at hand, all the usual disclaimers apply. I don't condone those who don't go through the official channels and notify electrical work.