But when the plasters got wet from the paint, it's then delaminated, so it obviously hasn't stuck to the bonding properly. I've experienced this problem before when papering, but never got to the bottom of it. The OP definitely shouldn't have PVA'd the wall prior to painting, but oddly, if it had trapped any moisture in, then the pva would have rewetted itself, and that would have stopped the paint sticking to it. The mist coat seals any dust into the new plaster, otherwise the new paint sits on top of the dust, and then peels off after some time.