Then you can treat the 32A Oven circuit as a radial, provided it is run in 6mm cable as is usual, and put two 13A outlets on it, one for each oven. These can be 13A FCUs with cable outlet if you like, or single sockets (not a double socket) with 13A fused plug for each oven. Cable to the sockets must be capoable of carrying a 32A load, as this is what it is fused at. Buy sockets by a major maker (MK, Crabtree, MEM) as the cables will be large and awkward, so you need big terminals.
You can retain the old cooker switch as the isolator for two ovens, so you can turn them off e,g, in the event of a fat fire or a fault.
As thsi is being done in a kitchen it is notifiable to your local Building Control office.