Thank you so much this worked, l had to link 25 to 26. Also switched CH button on the boiler to Timed.You have already noted cable you have circled blue is to thermostat just don't couple it up . I would replace that cable with a 3 core into fused connection and then to hive .
I take it the 5 core circled red goes to boiler?
I'f so connect as above with a single channel hive you will have one core too many just make spare electricity safe.
You don't need anything to ,20 that's a permanent live feed through board.
Room stat connection needs to be linked.
Also managed to disconnect the switch old thermostat now l do have 2 extra cable core. I will replace it with 3 core cable.
Thanks everyone.