Well, I finally got home and checked the piping and from what I can tell my son is correct, at least I'm 90% sure of this and would appreciate confirmation.
The reason I'm not 100% sure is that the manual for the Vaillant ecoTEC plus 637 System Boiler that we have shows more pipes than are actually connected to the boiler and they are slightly different, however this may be because we also have a Vaillant uniSTOR unvented cylinder to provide hot water.
Here's a photo of what I see under the boiler:
View media item 80805
Here's the relevant diagram from the installation manual:
View media item 80806
The two lagged 22mm pipes are the supply and return according to the sticker and the manual and this appears to be correct as the left hand (flow) pipe is connected to a Salus motorised valve, which appears to split between the hot water cylinder and the CH. The right hand (return) pipe has a magnaclean connected to it, so I assume it's normal for this type of thing to be connected to the return.
However, according to the sticker, the middle pipe is the gas supply and this isn't the case as I'm fairly sure that is the right hand 15mm pipe which appears to go through the garage wall to the gas meter. Hence I'm a little confused about how accurate the manual and stickers are as they don't completely match the actual pipe connections.
So, following the pipes from the boiler to the manifold, the left hand flow pipe connects at the right hand return side of the manifold and the right hand return pipe connects at the left hand flow side of the manifold. They are the wrong way around!
I did a little more testing and turned the heating on and could feel the left hand flow pipe at the boiler heat up quickly, while the right hand return pipe stayed relatively cool. I could follow this difference in heat along the pipes to the manifold, where as expected, the return bar was much hotter than the supply bar.