I am interpretting that "the pressure is released via the Magnaclean" to mean that you can reduce the pressure to say 1.5bar after sensor renewal, then wonder if the boiler E.vessel charge/precharge is checked as well and pumped up, if it is then gradually looses air through its schrader valve then maybe the other E.vessel is adversely affecting the pump "kick".
I also wonder why a second E.vessel is required as 9 UFH, 90MX16 mm loops + boiler contents shouldn't be more than 100 litres. A 8L E.vessel with precharge and filling pressures of 1.0bar/1.5bar will only rise to 2.0bar assuming 45C mean UFH temperature. Has the external E.vessel precharge pressure ever been checked?.