Andy you said
The problem is ... you have a vokera boiler
. Why is Vokera a bad/ poor quality boiler in you estimation.
Fazedup, if you were familiar with Excel operation, you would see rightaway what I am getting at. You may want to look at the boiler manual where it describes boiler operation during HW mode and then sit down and reaon why primary (not hot water) is going to radiators. I am going to invite OP to update his profile so a detailed answer can be supplied. If you want to know more, suggest open a discussion on Combustion chamber where answer will be provided.
Calderdale
He also ecchanged the diverter valve ....
I do not think he would have exchanged the diverter valve on the boiler as it is a large manifold requiring extensive stripdown. If he could not diagnose a simple fault like what you have, he would be in deep manure tackiling replacement of diverter/ flow section.
Fazedup
if the heat is going down the central heating pipework then i still say diverter or some kind of blockage stopping the water from going through the heat exchanger
I would say boiler requires a service as detailed in the manual. That should fix the problem.
Calderdale, put your email in your profile. Will send you an answer. Do not like posting details on open forums as this means lost work for other registered engineers and also have fear of uninitiated getting hurt 'practicing' a task off the forum.
Calderdale, are you sure the guy works for Vokera? Looks like he might be an independent (like me), but claims he works for Vokera. Vokera backup and techincal is one of the best. They may not want to 'know' about design faults but what manufacturer does. Thank you lucky stars you have a Vokera. This boiler responds well to a proper service (not the 15 minutes brushover) and all parts are a lot cheaper than other boilers of same quality. In two hours I normally overhaul (more than what service requires) Excels to near original spec using genuine parts.