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Is silicone grease now the standard application?
the front brakes have seized.
Neither have I. I've seen them a bit stiff as the grease has hardened, but not enough to cause brake binding. I use Stern Tube grease, which the supplier says is ceramic, and at least it's white like the original! Always been OK. But I'd be surprised if there were a problem with rubber or silicone grease, they won't rot the boots, and I doubt the pins are close enough to the action for heat to be a problem.I've never, ever seen caliper pin seizure due to grease failure, and that includes ceramic, rubber or silicone applications......all seizures have been due to water and dirt ingress over time.
Coppaslip isn't recommended if the dust boots are rubber as it will rot them. If the heat was so intense, I doubt if the boots themselves would stand it.
Of course, the pads could be stuck in their caliper lands - some designs are better than others in that respect.
John