Basic answer must be no, as we exceed 100% efficiency with heat pumps. So using a sterling engine on a gas supply we can exceed 100%.
But in real terms we are looking at the amount of fuel used to maintain the home as a comfortable temperature and much depends on how we transfer the energy into the compartment requiring heating.
So this boiler
seems to be wasting heat, but if it was not heating the carriages then the heat would simply be released into the atmosphere, so heating the carriages while at the station is not wasting a single Joule of heat.
There are 360 joules in a watt/hour, I have never understood why we use kWh, very misleading as it has nothing to do with time.
But what wastes the most energy is hysteresis, where the temperature is not kept stable, we want the room at for example 20°C not 18 to 22°C and ensuring the temperature is as wanted is far more important than the losses due to boiler efficiency.
The radiator has two methods to control the transfer heat into the room, one is control air flow, other is the radiator temperature so either we have a thermostatically controlled fan, or a thermostatic radiator valve (TRV) the fan is faster in response time to the TRV, so the fan in general works better, however the fan does not control the return temperature of the water in the same way as the TRV does, so with the fan we really want radiators in series, and with the TRV in parallel and in the main homes have the radiators in parallel so easier to use TRV heads to control the boiler output.
However there is a trade off between speed and installation cost, and nearly every central heating system is a compromise, the ideal system is rare, so banging in a condensing boiler which actually never boils anyway, with a system using fan assisted radiators may be less rather than more efficient.
What we need to look at is the system as a whole, not just one small part. And to only heat rooms when required to only the amount required even with a 50% efficient boiler is likely to use less energy than heating the rooms be they used or not to 10% hotter than required 24/7 even with a 120% efficient boiler (which does not boil anything so is not really a boiler to start with, and simply transfers heat from outside to inside).