but I have a little bit more information than the original poster.
Old fashioned CH system, i.e. hot water tank fed off boiler, not a combi.
Hot water kicks in fine, central heating not regardless of thermostat setting.
Have taken the motor of the HoneyWell motorised valve off, checked valve can move. Have managed by putting hot water control on to get some heat to rads, but boiler obviously turns off once tank is hot. Hot water hotter than would usually be.
Turned off at mains all central heating controls, switched off and restarted old boiler, no joy.
Suspect (hope) that the temperature thermostat on the wall (dial version) might have blown.
Had whole system checked out and lots of work done <3 years ago (would have been cheaper to get a new system the way it turned out). New heat exchange etc. fitted.
Now completely skint and need to try and fix this myself if at all possible. All help gratefully received.
Sorry OP for hi-jacking your thread, hopefully some info posted will be of use to you as well, think you'll need to describe what system you have for people to help you though.