If it is only 'pumping over' when the pump stops then raising the height of the vent will cure the problem.
If you don't have enough height in your roof to do this, then use 28mm pipe instead of 22mm on the way up to the highest point in your roof. This extra pipework will accommodate the sudden rush of water and so wont fall in the f+e tank, and thus not got re-airated.
As I have said some people on here may think this is rough, but it will cure your problem, if that is all that is wrong with your central heating.
Thanks Azazel. I've got plenty of height available. I suppose this is one way to test the theory that it's the regular discharge from the vent into the F+E that's aerating the water. If air continues to build up in the system then at least I can rule this out. I was thinking of rigging up a temporary extension using some clear plastic tubing to see what comes through - but B&Q want an arm and a leg for the stuff.