Good points!
Something about current being a flow of electrons which are all negatively charged and try to repel away from eachother, meaning more of the electrons gather around the outside of the copper, and the core of the conductor has very few. (that's one of the reasons why multi strand wires can carry more current than single strand/solids.)
Indeed. It's called 'surface effect' or 'skin effect'.
As such the current carrying capability of a conductor is more related to its circumference than its cross sectional area.
That is certainly the tendency in terms of impedance of the conductor, hence voltage drop for a given current, but not very significant at mains frequency. Current-carrying capacity (CCC)is a different matter, since it's primarily about temperature rise in the cable. Even if it's the peiphery of the conductor that carries most of the current, the generated heat will distribute throughout the whole of the cross sectional area (CSA), hence that also becomes a factor in determining temperature rise, hence CCC..
The circumference of a 2.5mm2 conductor is 2.8mm, while the circumference of a 6mm2 conductor is 4.3mm. The combined circumferences of TWO 2.5mm2 conductors is therefore 5.6mm, which means that this will carry MORE current than a single 6mm2 conductor.
As above, the calculations are not anything like as simple as that. However, the officially tabulated figurse for current carrying capacity are certainly anything but linear in terms of CSA. (using 'clipped direct' T&E cable as the example throughout), in terms of your example, it does roughly work as you say - 2 x 2.5mm² cables have a total CCC of 54A, as compared with 46A for 6mm². Moving up, 4 x 2.5mm² cables would have a CCC of 108A, compared with only 63A for 10mm².
I think the bottom line is that determination of CC (which is probably empirical, rather than theoretical) is a complicated matter - but you are certainly correct that, in a discussion as that here, people should be looking at the combined
current carryng capacities of two cables, not the combined CSA.
Kind Regards, John