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Excess air (extra air not utilised during combustion) is reduced considerably (to lower NOX emmisions and increase combustion efficiency slightly) with fully pre-mixed combustion and the gas/air mix is generally set around the red line. As a result combustion is not as complete as it could be.
Conventional burners have far more excess air and typically operate way to the right of the red line...with perhaps at least 80% extra air so combustion is cleaner and CO lower. The long flame burners also allow a more complete combustion process.
Fully pre-mix tend to produce no more than 150 ppm CO, conventional burners generally no more than 50 ppm CO. Over these limits and there's normally something wrong.
That doesn't mean they actually produce that. Most steamers I install produce less than 10 ppm in heating mode and less than 50 ppm on full blast DHW.
If I remember the tables correctly, breathing less than 30 ppm (for a limited amount of time) is not dangerous, so blowing these values into the open air is hardly going to bring the roof down.
You will find that the Gianonni Heat Exchangered Boilers (Stainless Steel) will produce more CO than their Aluiminnium counterparts, I personally blame it on a slightly more rapid flame chilling action of the former types
However nothing wrong with either
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