On a condensing gas boiler I don’t think the boiler will ever go into condensing mode without the radiators being balanced, the return temp will always be to high. This will be effect efficiency and hence gas usage.
Aye,
Assuming fixed speed pumps.
Modern pumps are proportional.
Modern boilers modulate.
But certainly, it's a lot of variation.
A modern boiler in non condensing mode is still more efficient than an old non condensing boiler.
Heating a large space (or all zones) will still be in condensing mode.
The problem comes when the majority of the rads are satisfied and flow rates drop, knocking the boiler out of condensation.
But, do you hobble the existing system to cope with the low heat input case? I don't think so. Let the system be as quck as it can be, then you'll have the boiler running less and thus you can keep the on-off fluctuations to a min.
However, there is a huge push for low temp heating and low heat loss housing design and retrofit which needs high flow rates and low water temps in big rads.
I find it counter intuitive to upgrade the system for higher potential heat output and then stand on its throat in the name of balancing.
Better to slow the flow at the pump, than at the emmiter?
Complex problems. Not easily solved by rules of thimb and look up charts the industry is used too.
(Sorry to the OP for going OT!)