EvoHome does wire into boiler circuit. Each wireless TRV connects to a central controller which in turn tells the boiler when to run. You set the times and temperatures of each room, so bedrooms can remain cold during the day, and living room cold at night. But before you decide that's what you want, look at the price.
In theory the modern boiler does not need an electric thermostat, as each room warms up the TRV closes and the return water gets warmer, the boiler output is reduced to match the return water temperature until it can't reduce any more, when it switches off, after a set time it tries again, if the return water is still hot then it increases the time before re-trying, if not it decreases the time. No longer do you have one radiator without a TRV you have a by-pass valve instead.
So only reason for an electric thermostat is to stop boiler firing up when it is likely to be a fine day. So thermostat placed where it will get morning sun.
However in the real world this system is not all it's cracked up to be. Mainly because not installed correctly to start with. So we add electric thermostats and timers. What messed up out central heating was the so called energy saving bulb. Before the tungsten bulb would transmit radiated heat at night when room was used so setting the room to 18°C was great all day long. But without the tungsten bulb we want the room at 18°C in the day and 20°C at night. Although you can get TRV's with stand alone electronic heads so the temperature can change at different times of the day, these can mess up the anti-cycle software built into the boiler.
So what I and many others do is use a thermostat in the main room so temperature can vary through the day, but other rooms are then a little bit of hit and miss. I in fact use two wireless thermostats one in the living room timed to control during the day and one in bed room timed to control at night. It does work of sorts, but not all the time. Looked at EvoHome and decided too expensive.