A 'Y' plan system has a 3-port valve, which can only close off one outlet port at a time, meaning there is always one outlet port open.
If you then add an additional 2-port valve, when that valve opens for whatever it is supplying (you haven't told us what that is) and it switches the pump & boiler on, one of the outlet ports fed by the 3-port valve will also allow water to flow through it whether it is required or not. So, using a combination of 3-port and 2-port valves on the same system doesn't work. For multiple zones you would need an S-Plan.
So as muggles says, you need to explain what you are trying to achieve with this additional valve.
What regulations are you referring to?