"Heat rises". How far above floor are your TRV (19.0°), your table (19.6°) and the wall thermostat (20.5°), I wonder?
This is clearly the problem in the hall, TRV is closer to the front door and lower, TRV 16°C and wall 20°C.
Living room, wall thermostat 20.5°C closer to centre of house, and about 5' high, table 20°C 3' high, radiator behind me 20°C 9" high and against the south wall, and radiator on west wall, 18.8°C again 9" from floor, since 1:35 am the heating has not been running for a while, radiators stone-cold.
When I moved from tungsten lighting to CFL, I found that the time clock and thermostat were no longer good enough, I wanted it warmer in the evening, and I fitted my first programmable thermostat. We had 6 bulbs in the room, varied sometimes 40 watts, sometimes 60 watts, which you would not think would generate much inferred heat, which since thermostat, was around the corner, after the arch between dinning room and living room, it would not get any inferred heat from living room lights.
It does raise the question did tungsten lights save energy? As I now set the thermostat to 20°C in the day and 22°C in the evening, so the room air is 2°C warmer to what it would have been with tungsten lights, so more heat will escape. Since electric is more expensive to oil or gas money wise, LED lamps help, but not so sure energy wise.
As to how good the old mechanical thermostats were compared with modern electronic ones, I don't know? The old mechanical TRV heads were not even calibrated in °C. A bit of guess work what *123456 mean. And I have the TRV head today set higher than the wall thermostat as don't really want the radiator to turn off, while boiler still running. Unless boiler only running for DHW.
But I have considered other forms of heating, but although a storage radiator may reduce the hysteresis, it could also result in the room being too warm. And electric even at 8.5p/kWh overnight is more expensive compared with oil. And for inferred using electric at peak rate, so don't want that.
However, for those will only electric heating, the situation changes.