Why should not any of the TRVs be able to turn the boiler on?
Because I have not paid for TRV heads which link to a hub. I got 5 of these,

and had 4 of these

taken from my late mothers house, the latter claimed to work with Nest, however one they worked the wrong way around, the wall thermostat told the TRV head the temperature to set them to, and although changing Nest Gen 3 with the app would also change the TRV head at the same time, set schedules failed to change the TRV setting, so had to use them in isolation.
The Wiser head
and Kasa head
can connect to a hub or wall thermostat, but the Kasa wall thermostat is hard-wired, so I did not have wiring where it would need fitting, so only the Wiser head connects to a hub, and so can turn on the boiler (and of course also allow it to stop) and since two far away from hub, it needs a socket adaptor to relay the signal, so will not link to boiler if there is a power cut.
Both the Wiser and Kasa can have remote sensors, with Wiser putting a wall thermostat and TRV in the same room, the wall thermostat takes control, with Kasa there is a sensor available so it can sense away from the radiator, so if radiator on an outside wall, it does not open too soon.
This I suppose is a problem, each TRV head has different features, the eQ-3 head will detect a rapid drop in temperature, which would happen if the window or door opened, and turn off for a time you the user has set, handy when unloading shopping from the car. Tried the geo-fencing with both the Energenie TRV and Nest Gen 3 wall thermostat, it was a failure, Energenie had anti hysteresis software which was OTT, and Nest turned the heating back on basically just before you came through the door, so heating running when one gets home, but home still cold. Not tried with Wiser, know it uses IFTTT same as Energenie, but never tried.
There is an article on DIYnot
on the aqara-radiator-thermostat-w600 but it does not compare it with any other make, so little more than an advert.
I wish there was a comparative site,
Which have one and
Another one here the early guides said how Nest could work with Energenie which it will not, so how much can you trust the guides?
If I need any more, I will use Drayton Wiser, as it does seem the best of the bunch, but I learnt the hard way, I trusted Nest, and they must be around the worst smart thermostat you can buy in the UK, USA version very different.