One has to remember this is a 3ph circuit even though there is only access to a 1/3 of it in the form of L&N and for our purposes lets assume we are using the red or brown phase. However if there is no stated reference point we can nominate one. This is usually the star point or N.That's largely what I expected you to say, so it still leaves me rather confused!
If L-N is about 235V, N-CPC is 0V (assumed due to it being TN-C-S) and CPC-earth_rod (winston has forced me to type a few extra characters ) is 50-200V, then one would expect (assuming everything is in phase, which surely it must be?!) that L-earth_rod would be 285V - 435V, wouldn't one?
If that were the case, your 0-300V measurement of L-earth_rod would seem very low; I can't see any reason to suspect that the earth rod would ever be at a higher potential than the DNO-derived CPCs, so the very lowest L-earth_rod voltrage one would expect to see would be the L-N voltage (235V or whatever), wouldn't it? ... and, even at the very bottom of your range of observed CPC-earth_electrode measurements (i.e. 50V), the expected L-earth_rod voltage wouldn't (at 285V) be much under 300V (which you say is roughly the highest L-earth_rod voltage you've observed.
Kind Regards, John
As an example:
Let's make some assumptions that all 3 phase voltages are 230V [called R, Y, B] and points 1 & 2 are 100V all referred to N.
Now lets make the reference at point 1 [let's not get into how or why] then N = 100v, red=130V, Yellow= 293V
Likewise
Use 2 as the reference at point [let's not get into how or why] N = 100v, red=293V, Yellow= 130V
Furthermore use Y as the reference point [let's not get into how or why] N = 230v, red=400V, Yellow= 0V
The reference point can be anywhere within the black triangle or even outside it if the loads are very reactive, for your calculations to be correct it would have to be directly antiphase with L, I've shown is as point 3 at 100v from N. Therefore N = 100v, red=330V, and if its of interest Yellow= 200.6V with resistive loads it could never exceed: N=115V, L=345V [& Y would be 200V] unless there is any additional stray voltage, bearing in mind this is derived from HV and could concievably be floating on 11KV
All voltages quoted are rounded to some extent.