If you go to a prv dripping and cold water expansion vessel has no charge. Do most people recharge? We have to depressorise and remove to do that. So it it easyier to just fit a new vessel ?
Nope - dead quick and easy to re-pressurise with the correct type of pump, though if it is a remote EV (not an in cylinder baffle type) then it should really be done at service time by a qualified Unvented chap.
As long as you can get the connector from the pump to the top of it then it should be able to be done in situ, I have a stirrup type pump that has a 3m hose on it for exactly that kind of thing. if not then it's a drain down and remove.
Don't forget to balance out the pre-charge to the mains pressure and expansion etc.
A stainless steel UV cylinder with its pressure reducing valve set to 3.0bar (or a recommended 2.8bar) and a EV sized to 10% of the UV cylinder's capacity will have a final pressure of just over 4.0bar if fully heated from 5C to 65C, its expansion relief valve might be typically set to 6.0bar and its T&PRV set to 8.0bar, example, below, of final pressure.
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