I was told off on this site for suggesting no manufacturer would put the electrical connection box within a gas sealed compartment, it would require the use of special cable and glands and simply does not make sense, however I am told in fact they do.
As to 4 core cable I am not sure if AC supply in the same cable as the eBUS would be a good idea, I would use two independent cables and ali-tube would seem a good idea except for the gas tight problem.
The idea of a thermostat is the first question? If the thermostat is simply to turn off boiler when all rooms are satisfied then simple on/off is good enough in most cases, but if the thermostat is to control the house temperature then it needs to be the modulating type, the more I read about boilers modulating their output the more confused I get.
This account seems to say boilers work best flat out, but other accounts report how they are more efficient when modulated, however it does seem there are losses every time a boiler turns off with heat lost out of the flue, so where a boiler can be modulated then it should be, not simply turned on/off.
However the TRV will modulate most boilers, where the thermostat simply turns off the boiler as warm weather arrives and the TRV controls the output it can be argued no need for a modulating wall thermostat, however where the thermostat only turns off the heating on warm days, seems little point in having a thermostat connected to your phone, having electronic TRV heads connected to phone yes, but not the wall thermostat. Unless of course that thermostat in turn controls the TRV heads like with Nest and EvoHome.
So what is the whole point of Hive, it is not modulating, it does not connect with the electronic TRV heads, it just seems to be snake oil, I am sure it works great with hot air central heating systems, as used in USA, but for British systems is has a very limited use, specially as some models don't have volt free contacts. There is a whole list of boilers that can't use Hive, specially Bosch, why so many want to fit it I don't know, must have the same sales guy who sold all those socket protectors that defeated the British socket shutters?