Your design will work, but is dependent on size of pipe you are teeing into, the size and length of new pipe run and the size of the new rads. More importantly, it contravenes building regs to do what you propose.
The entire system is runnin gon Hep2o 10mm pipework. So the tee will be from that. In terms of length from Tee, it will be just behind the wall on the other side. So it will be about 60-80cm for each pipe. The new radiators will be one double convector 1200 x 600 and another 1200 x 500. I checked the load and output of the boiler and the current consumption of the existing radiators are no more than 8kW and the boiler has output of 18kW.
What would be the correct way to add the 2 radiators that doesnt contravene building regs?